Efficiency of a ruthenium catalyst in metathesis reactions of sulfur-containing compounds |
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| Authors: | Spagnol Gaëlle Heck Marie-Pierre Nolan Steven P Mioskowski Charles |
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| Institution: | CEA-CE Saclay, Service de Marquage Moléculaire et de Chimie Bio-organique, Bat 547, Département de Biologie Joliot Curie, 91191 Gif sur Yvette Cedex, France. |
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| Abstract: | reaction: see text] 1,3-Dimesitylimidazol-2-ylidene ruthenium benzylidene catalyst (RuCl2(=C(H)Ph)(PCy3)(IMes)) has been successfully employed in ring-closing metathesis reactions of acyclic diene sulfides, disulfides, and dithianes and in self-cross metathesis reactions of ene-sulfides, thioethers, and thiols. |
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