Nickel-catalyzed cyclizations and couplings with vinylzirconium reagents |
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Authors: | Ni Yike Amarasinghe Kande K D Montgomery John |
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Affiliation: | Department of Chemistry, Wayne State University, Detroit, Michigan 48202-3489, USA. |
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Abstract: | [reaction: see text] 1,3-Dienes were prepared by a variety of nickel-catalyzed couplings and cyclization processes. Intermolecular or partially intramolecular couplings of alkynes, vinylzirconium reagents, and either aldehydes or enones efficiently proceeded to generate a broad range of functionalized dienes. |
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