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Direct Growth of Cobalt Hydroxide Rods on Nickel Foam and Its Application for Energy Storage
Authors:Dr. Rahul R. Salunkhe  Dr. Bishnu Prasad Bastakoti  Dr. Chun‐Tsung Hsu  Dr. Norihiro Suzuki  Prof. Dr. Jung Ho Kim  Prof. Dr. Shi Xue Dou  Prof. Dr. Chi‐Chang Hu  Prof. Dr. Yusuke Yamauchi
Affiliation:1. World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1‐1 Namiki, Tsukuba, Ibaraki 305‐0044 (Japan), http://www.yamauchi‐labo.com;2. Laboratory of Electrochemistry and Advanced Materials, Department of Chemical Engineering, National Tsing Hua University, Hsin‐chu 30013 (Taiwan);3. International Center for Young Scientists (ICYS), National Institute for Materials Science (NIMS), 1‐2‐1 Sengen, Tsukuba, Ibaraki 305‐0047 (Japan);4. Institute for Superconducting and Electronic Materials, University of Wollongong, Innovation Campus, North Wollongong, NSW 2500 (Australia);5. Faculty of Science and Engineering, Waseda University, 3‐4‐1 Okubo, Shinjuku, Tokyo 169‐8555 (Japan)
Abstract:The present work reports synthesis of cobalt hydroxide (Co(OH)2) rods on nickel foam and its supercapacitor application. Hierarchical Co(OH)2 rods with length of approximately 3.5 μm and diameter of approximately 400 nm were prepared by one‐step, simple, and inexpensive chemical‐bath‐deposition method. The direct growth of Co(OH)2 rods on the Ni foam gave three dimensional (3D) structure for easy access of electrolyte throughout material surface. Also, well‐adhered interface between Co(OH)2 rods and Ni‐foam surface gave better conduction channels. Detailed electrochemical study was performed by using cyclic voltammetry and galvanostatic charge/discharge measurements. The results demonstrate that Co(OH)2 rods on Ni foam are efficient electrodes for supercapacitor application.
Keywords:chemical‐bath‐deposition method  cobalt  nanostructures  rods  supercapacitors
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