Kinetics of the reaction of peracetic acid with naphthalene and anisol |
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Authors: | A A Akhrem P A Kiselev and D E Metelitza |
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Institution: | (1) Institute of Physical Organic Chemistry, Academy of Sciences of the BSSR, Minsk |
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Abstract: | The kinetics of the bimolecular reaction of peracetic acid with naphthalene (58–75 °C) and anisol (37.5–50.5 °C) have been studied in 2 1 dichlorethane-acetic acid. The rate constans for naphthalene and anisol are Knapht=2.0×109 exp (–21000/RT) 1 mol–1 sec–1, Kanis=6.3×108 exp (–17000/RT) 1 mol–1 sec–1.
![Icy](/content/x346476375163021/xxlarge1048.gif) ![zcy](/content/x346476375163021/xxlarge1079.gif) ![ucy](/content/x346476375163021/xxlarge1091.gif) ![chcy](/content/x346476375163021/xxlarge1095.gif) ![iecy](/content/x346476375163021/xxlarge1077.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![iecy](/content/x346476375163021/xxlarge1077.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![bcy](/content/x346476375163021/xxlarge1073.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![mcy](/content/x346476375163021/xxlarge1084.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![iecy](/content/x346476375163021/xxlarge1077.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![ucy](/content/x346476375163021/xxlarge1091.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![yacy](/content/x346476375163021/xxlarge1103.gif) ![rcy](/content/x346476375163021/xxlarge1088.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![rcy](/content/x346476375163021/xxlarge1088.gif) ![iecy](/content/x346476375163021/xxlarge1077.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![tscy](/content/x346476375163021/xxlarge1094.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![dcy](/content/x346476375163021/xxlarge1076.gif) ![ucy](/content/x346476375163021/xxlarge1091.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![scy](/content/x346476375163021/xxlarge1089.gif) ![ucy](/content/x346476375163021/xxlarge1091.gif) ![scy](/content/x346476375163021/xxlarge1089.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![scy](/content/x346476375163021/xxlarge1089.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![fcy](/content/x346476375163021/xxlarge1092.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) (58–75 °C) ![acy](/content/x346476375163021/xxlarge1072.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![zcy](/content/x346476375163021/xxlarge1079.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) (37.5–50.5 °C) ![scy](/content/x346476375163021/xxlarge1089.gif) ![rcy](/content/x346476375163021/xxlarge1088.gif) ![iecy](/content/x346476375163021/xxlarge1077.gif) ![dcy](/content/x346476375163021/xxlarge1076.gif) ![dcy](/content/x346476375163021/xxlarge1076.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![khcy](/content/x346476375163021/xxlarge1093.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![rcy](/content/x346476375163021/xxlarge1088.gif) ![ecy](/content/x346476375163021/xxlarge1101.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![ucy](/content/x346476375163021/xxlarge1091.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![scy](/content/x346476375163021/xxlarge1089.gif) ![ucy](/content/x346476375163021/xxlarge1091.gif) ![scy](/content/x346476375163021/xxlarge1089.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![scy](/content/x346476375163021/xxlarge1089.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) (2 1). ![Pcy](/content/x346476375163021/xxlarge1055.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![ucy](/content/x346476375163021/xxlarge1091.gif) ![chcy](/content/x346476375163021/xxlarge1095.gif) 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![rcy](/content/x346476375163021/xxlarge1088.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![scy](/content/x346476375163021/xxlarge1089.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) ![rcy](/content/x346476375163021/xxlarge1088.gif) ![iecy](/content/x346476375163021/xxlarge1077.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![tscy](/content/x346476375163021/xxlarge1094.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![dcy](/content/x346476375163021/xxlarge1076.gif) ![kcy](/content/x346476375163021/xxlarge1082.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![scy](/content/x346476375163021/xxlarge1089.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![fcy](/content/x346476375163021/xxlarge1092.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![zcy](/content/x346476375163021/xxlarge1079.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) : (![ncy](/content/x346476375163021/xxlarge1085.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![fcy](/content/x346476375163021/xxlarge1092.gif) ![tcy](/content/x346476375163021/xxlarge1090.gif) ![acy](/content/x346476375163021/xxlarge1072.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) )=2,0×109 ![iecy](/content/x346476375163021/xxlarge1077.gif) ![khcy](/content/x346476375163021/xxlarge1093.gif) (–21000/RT) /![mcy](/content/x346476375163021/xxlarge1084.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) . ![scy](/content/x346476375163021/xxlarge1089.gif) ![iecy](/content/x346476375163021/xxlarge1077.gif) . (![acy](/content/x346476375163021/xxlarge1072.gif) ![ncy](/content/x346476375163021/xxlarge1085.gif) ![icy](/content/x346476375163021/xxlarge1080.gif) ![zcy](/content/x346476375163021/xxlarge1079.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) )=6,3 108 ![iecy](/content/x346476375163021/xxlarge1077.gif) ![khcy](/content/x346476375163021/xxlarge1093.gif) (17000/RT) /![mcy](/content/x346476375163021/xxlarge1084.gif) ![ocy](/content/x346476375163021/xxlarge1086.gif) ![lcy](/content/x346476375163021/xxlarge1083.gif) . ![scy](/content/x346476375163021/xxlarge1089.gif) ![iecy](/content/x346476375163021/xxlarge1077.gif) .
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