Absolute asymmetric photocyclization in chiral diarylethene co-crystals with octafluoronaphthalene |
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| Authors: | Morimoto Masakazu Kobatake Seiya Irie Masahiro |
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| Institution: | Department of Chemistry, Rikkyo University, Nishi-Ikebukuro 3-34-1, Toshima-ku, Tokyo 171-8501, Japan. m-morimoto@rikkyo.ac.jp |
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| Abstract: | A photochromic diarylethene containing naphthyl groups formed a chiral crystal when co-crystallized with octafluoronaphthalene, although both molecules are achiral, and underwent highly enantioselective photocyclization owing to the conformational confinement in the crystal. |
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