Mössbauer study of Cd0.1Ni0.9Sn y Fe2?2y O4 ferrites

Mössbauer spectra of Cd_0.1Ni_0.9Sn_yFe_2?2yO₄ (y=0.0 to 0.5) ferrite system have been studied. The spectra suggest the existence of two hyperfine fields, one due to Fe³⁺ tetrahedral (A) site ions and the other due to Fe³⁺ octahedral (B) site ions. The variation of isomer shift, quadrupole interaction and internal magnetic fields of⁵⁷Fe³⁺ ions in both A and B sites have been determined as function of tin concentration. The systematic decrease in Curie temperature observed in the above system with tin concentration is explained on the basis of exchange interaction.