Charge ordering in lithium vanadium phosphates: electrode materials for lithium-ion batteries |
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| Authors: | Yin Shih-Chieh Grondey Hiltrud Strobel Pierre Huang Huan Nazar Linda F |
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| Affiliation: | Department of Chemistry, University of Waterloo, Ontario, Canada N2L 3G1. |
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| Abstract: | The delithiation process in monoclinic Li3V2(PO4)3 has been determined by powder neutron diffraction coupled with 7Li solid-state NMR techniques. Charge ordering of vanadium (V3+/V4+) was observed in Li2V2(PO4)3 as shown by the gray and blue V-O octahedra, respectively, indicating that the electrons are pinned in this phase and hence transport is limited. |
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