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On dispersion force correction terms in perturbed equations of state
Authors:Ivo Nezbeda  
Abstract:The first-order correction term for the contribution of dispersion forces in a perturbation expansion has been analyzed using computer simulation and perturbation theory results. It turns out that simple approximations used to make an analytic evaluation of the correction integral possible may result, ironically, in more complicated (and erroneous) behavior in comparison with the exact result.
Keywords:Statistical mechanics   Perturbed equations of state   Square-well fluid   Triangular-well fluid   Mean-field corrections
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