Photochemically induced coupling reaction of triarylstibines with olefins |
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| Authors: | Naoki Kakusawa Takashi Tsuchiya Jyoji Kurita |
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| Institution: | Faculty of Pharmaceutical Sciences, Hokuriku University, Kanazawa 920-1181, Japan |
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| Abstract: | Photoreaction of triarylstibines with styrenes resulted in the formation of 2-aryl-1-phenylethanols accompanied by air oxidation. Formation of the products has been explained by the valence expansion of the oxygen-antimony-styrene complex to a five-valent intermediate, followed by reductive coupling. |
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| Keywords: | antimony and compounds photochemistry coupling reactions oxidation |
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