|
|||||
|
|
Hydration behavior of mixed ligand chromium complexes. Part I: partial molar volumes and partial molar adiabatic compressibilities of oxalato and mixed oxalato — Ethylxanthato chromate(III) complexes |
|
| Authors: | S P Bhattacharya B B Nath |
| Institution: | (1) Department of Chemistry, Visva-Bharati University, 731 235 Santiniketan, West Bengal, India |
| Abstract: | Densities and ultrasonic velocities in aqueous solutions of cis-KCr(ox)2(H2O)2], K3Cr(ox)3] and KSSCOC2H5 and a mixed ligand complex K2Cr(ox)2SSCOC2H5], where SSCOC2H5 is the ethylxanthate ligand, have been measured at 25, 35 and 45°C. Limiting partial molar volumes, partial molar adiabatic compressibilities and hydration numbers of the complex salts as well as of the ligand have been calculated. The implication of the findings are discussed. |
| Keywords: | Partial molar volume and adiabatic compressibility hydration number potassium ethylxanthate dioxalato ethylxanthato chromate ion K[Cr(ox)2(H2O)2] K3[Cr(ox)3] K2[Cr(ox)2SSCOC2H5] |
| 本文献已被 SpringerLink 等数据库收录！ | |