Indium mediated allylation of glyoxylate oxime ethers, esters and cyanoformates |
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Authors: | Ritson Dougal J Cox Russell J Berge John |
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Institution: | School of Chemistry, University of Bristol, Cantock's Close, Bristol, UKBS8 1TS. r.j.cox@bris.ac.uk |
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Abstract: | An indium mediated procedure has been developed for the allylation of activated O-functionalised oximes and nitriles as exemplified by a variety of glyoxylate derivatives. This method gives the corresponding free (or protected) amine in a one pot-process. The method is regiospecific and is carried out under remarkably mild conditions so that even oxime esters can be subjected to the typical reaction conditions. |
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