Photolysis of alpha-azidoacetophenones: trapping of triplet alkyl nitrenes in solution |
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Authors: | Mandel S M Krause Bauer J A Gudmundsdottir A D |
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Institution: | Department of Chemistry, University of Cincinnati, Ohio 45221-0172, USA. |
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Abstract: | reaction: see text] Selective excitation of the ketone chromophore in alpha-azidoacetophenones, 1, leads to intramolecular triplet energy transfer to the azido group, which forms the corresponding triplet alkyl nitrene, 2. Azides 1 also undergo alpha-cleavage to form benzoyl and methyl azido radicals in competition with nitrene formation. Thus the major photoproduct, 2-benzoylamino-1-phenylethanone, 3, comes from trapping of 2 with a benzoyl radical. This appears to be the first observation of bimolecular trapping of triplet alkyl nitrenes in solution. |
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