Analytical approach to the study of molecular rotation in liquids |
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Authors: | James McConnell |
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Institution: | Dublin Institute for Advanced Studies, Dublin 4, Ireland. |
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Abstract: | The rotational thermal motion of molecules is investigated by the combined use of the stochastic rotation operator, the Euler-Langevin equations of Brownian motion and the Krylov-Bogoliubov method of solving nonlinear differential equations. The results are applied to dielectric relaxation by orientational polarization and to nuclear magnetic relaxation by a variety of mechanisms. |
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