The [1,5]-Brook rearrangement: an initial application in anion relay chemistry |
| |
| Authors: | Smith Amos B Xian Ming Kim Won-Suk Kim Dae-Shik |
| |
| Affiliation: | Department of Chemistry, Laboratory for Research on the Structure of Matter, and Monell Chemical Senses Center, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA. smithab@sas.upenn.edu |
| |
| Abstract: | The [1,5]-Brook rearrangement proceeds efficiently in a series of hydroxyl dithiane substrates with sodium and potassium bases; less effective are lithium bases. That the mode of silyl migration is intramolecular was demonstrated by a crossover experiment. Finally, the tricomponent anion relay chemistry (ARC) coupling tactic was demonstrated employing the [1,5]-Brook rearrangement. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
