| 镉(Ⅱ)与对乙酰氨基苯甲酸、4，4′-联吡啶配位聚合物的合成、晶体结构及荧光性质 |
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| 引用本文： | 杨颖群,李昶红,李 薇,易正戟.镉(Ⅱ)与对乙酰氨基苯甲酸、4，4′-联吡啶配位聚合物的合成、晶体结构及荧光性质[J].无机化学学报,2009,25(7):1304-1307. |
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| 作者姓名： | 杨颖群 李昶红 李 薇 易正戟 |
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| 作者单位： | 1. 衡阳师范学院化学与材料科学系,衡阳,421008
2. 湖南工学院化学化工系,衡阳,421002 |
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| 基金项目： | 湖南省重点学科建设项目，湖南省科技厅资助项目 |
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| 摘 要： | The complex {Cd2(C9H8O3N)2(CH3COO)2(4,4′-bipy)2]·(4,4′-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4′-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals, forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4′-bipy molecules and the complex molecule forms an one-dimensional double-chain structure. The luminescent properties of the complex were studied. CCDC: 734878.
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| 关 键 词： | 镉(Ⅱ)配合物 对乙酰氨基苯甲酸 液层扩散法 晶体结构 cadmium(Ⅱ) complex |
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