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Kinetics and mechanism of the deep electrochemical oxidation of sodium diclofenac on a boron-doped diamond electrode
Authors:M. D. Vedenyapina  D. A. Borisova  K. -H. Rosenwinkel  D. Weichgrebe  P. Stopp  A. A. Vedenyapin
Affiliation:1713. Zelinsky Institute of Organic Chemistry of Russian Academy of Sciences, Moscow, 119991, Russia
2713. Institute of Sanitary Engineering & Waste Management, Leibniz University, 30167, Hannover, Germany
Abstract:The kinetics and mechanism of the deep oxidation of sodium diclofenac on a boron-doped diamond electrode are studied to develop a technique for purifying wastewater from pharmaceutical products. The products of sodium diclofenac electrolysis are analyzed using cyclic voltammetry and nuclear magnetic resonance techniques. It is shown that the toxicity of the drug and products of its electrolysis decreases upon its deep oxidation.
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