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| BATPPH_2及其Zn配合物与环糊精的超分子体系研究 | |
| 引用本文： | 王武林,赵鸿斌,宁静恒,胡 羽,张 辉,陆旭甲,叶领云.BATPPH_2及其Zn配合物与环糊精的超分子体系研究[J].无机化学学报,2010,26(11):2025-2032. |
| 作者姓名： | 王武林 赵鸿斌 宁静恒 胡 羽 张 辉 陆旭甲 叶领云 |
| 作者单位： | 1. 湘潭大学化学学院环境友好化学与应用省部共建教育部重点实验室,湘潭,411105 2. 湘潭大学化学学院环境友好化学与应用省部共建教育部重点实验室,湘潭,411105;东莞理工学院化学与环境工程学院,东莞,523808 3. 长沙理工大学化学与环境工程学院,长沙,410076 4. 东莞理工学院化学与环境工程学院,东莞,523808 |
| 基金项目： | 湖南省自然科学基金，广东省自然科学基金 |
| 摘 要： | 设计合成了5-(4-苯甲酰亚胺基苯基)-10,15,20-三苯基卟啉(BATPPH2)及其锌配合物(BATPPZn),并通过1HNMR、IR、UV-Vis、元素分析等方法对化合物的结构加以确认。在中性磷酸盐缓冲溶液中,以荧光光谱法、紫外可见分光光度法和1HNMR法分别研究了BATPPH2和BATPPZn与α,β,γ-环糊精相互作用形成的超分子体系。利用双倒数曲线法计算了BATPPH2-CD和BATPPZn-CD超分子体系的包结常数,结果表明BATPPH2和BATPPZn与γ-CD的包结常数(K1γ-CD,K2γ-CD)最大,γ-CD表现出最强的包结能力,Zn2+的配位作用使包结物的稳定性降低。 |
| 关 键 词： | 卟啉 环糊精 超分子体系 荧光光谱法 紫外可见分光光度法 核磁共振氢谱法 |
Supramolecular Systems of BATPPH2 and Its Zn Complex with Cyclodextrins |
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| WANG Wu-Lin,ZHAO Hong-Bin,NING Jing-Heng,HU Yu,ZHANG Hui,LU Xu-Jia and YE Ling-Yun.Supramolecular Systems of BATPPH2 and Its Zn Complex with Cyclodextrins[J].Chinese Journal of Inorganic Chemistry,2010,26(11):2025-2032. | |
| Authors: | WANG Wu-Lin ZHAO Hong-Bin NING Jing-Heng HU Yu ZHANG Hui LU Xu-Jia and YE Ling-Yun |
| Institution: | Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105,Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105; College of Chemical and Environmental Engineering, Dongguan University of Technology, Donggu,College of Chemistry and Environment Engineering, Changsha University of Science and Technology, Changsha 410076,Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105,Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105,Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105 and College of Chemical and Environmental Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808 |
| Abstract: | |
| Keywords: | porphyrin cyclodextrin supramolecular fluorescence spectroscopy ultraviolet-visible spectrometry 1H NMR |
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