| 关于合成Ge—132所用Ge原料其残留无机锗的问题 |
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| 引用本文： | 李贺成,王铁艳.关于合成Ge—132所用Ge原料其残留无机锗的问题[J].广东微量元素科学,1999,6(12):18-21. |
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| 作者姓名： | 李贺成 王铁艳 |
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| 作者单位： | 北京有色金属研究总院!北京100088 |
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| 摘 要： | Ｇｅ－１３２中的无机锗含量是一个重要的质量指标。它主要来自ＧｅＨＣｌ３中的ＧｅＣｌ４，而无论哪种锗原料合成Ｇｅ－１３２，ＧｅＨＣｌ３都是中间产物。与用金属Ｇｅ和ＧｅＯ２制备Ｇｅ－１３２的工艺比较，用ＧｅＯ２的盐酸溶液比用金属Ｇｅ在高温下与ＨＣｌ气反应制备ＧｅＨＣｌ３更利于降低Ｇｅ－１３２中残留的无机锗含量。
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| 关 键 词： | Ge－132 合成 锗原料 无机锗残留 有机锗药物 |
| 修稿时间： | 1999-06-27 |
Relation between Inorganic Germanium Remained in Ge-132 Synthesis from Different Raw Materials |
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| LI He-cheng,WANG Tie-yan,YUAN Qin.Relation between Inorganic Germanium Remained in Ge-132 Synthesis from Different Raw Materials[J].Trace Elements Science,1999,6(12):18-21. |
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| Authors: | LI He-cheng WANG Tie-yan YUAN Qin |
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| Abstract: | Inorganic germanium in Ge-132 is an important quality index.GeHCl 3 is the only intermediate for preparation of Ge-132 from different raw materials.Inorganic germanium in Ge-132 originates from GeCl 4 in GeHCl 3.It shows that GeHCl 3 made by GeO 2 which suspended in the solution of hydrochloric acid is better than the method by dry hydrogen chloride reacts with the element Ge at high temperatures.The former can contribute to a better reducing of Ge 4+ in Ge-132. |
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| Keywords: | Ge-132 inorganic germanium synthesis |
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