Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXIII.1 Correlation Analysis of Solvation Effects in Monomolecular Heterolysis of 1-Bromo-1-methylcyclopentane, 1-Bromo-1-methylcyclohexane, and 2-Bromo-2-methyladamantane |
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Authors: | G. F. Dvorko I. V. Koshchii E. A. Ponomareva |
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Affiliation: | (1) Kievskii politekhnicheskii institut National Technical University of Ukraine, Kiev, Ukraine |
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Abstract: | The rate of heterolysis of 1-bromo-1-methylcyclopentane and 1-bromo-1-methylcyclohexane is determined by the equation v = k[RBr], mechanism E1. Comparative correlation analysis of solvation effects in heterolysis of these substrates and 2-brom-2-methyladamantane was performed. |
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