The induced circular dichroism of helically shaped racemic bilatrienes |
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| Authors: | D. Krois H. Lehner |
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| Affiliation: | (1) Institut für Organische Chemie der Universität Wien, A-1090 Wien, Österreich |
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| Abstract: | Summary The imperfect mirror image relationship of the circular dichroism of (M) and (P) helical biliverdins bound to a homochiral entity (ICD) has been studied using the kinetically stable racemates (M+P)2 and (M+P)3. The phenomena associated with and eventual implications for the interpretation of ICD spectra of naturally occurring kinetically labile biliverdins in terms of chiral recognition are discussed.Dedicated to ProfessorKarl Schlögl on the occasion of his 70th birthday |
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| Keywords: | Induced circular dichroism Biliverdins Chiral discrimination Chiral recognition |
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