| 饱和漆酚冠醚聚合物的研究 |
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| 引用本文： | 黄载福,束家有,喻宗源.饱和漆酚冠醚聚合物的研究[J].高分子学报,1984,0(3):220-222. |
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| 作者姓名： | 黄载福 束家有 喻宗源 |
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| 作者单位： | 武汉大学化学系
(黄载福)，现在武汉化工学院工作
(束家有)，现在湖北省化学研究所工作(喻宗源) |
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| 摘 要： | <正> 冠醚具有选择性络合阳离子的能力,引起了人们极大的兴趣。高分子冠醚或冠醚高分子固定化,从应用角度考虑,不仅毒性降低,而且易于回收和反复使用,这是扩大冠醚应用范围的一个重要途径,也是研究冠醚化学的新动向,smid等对冠醚高聚物的合成和络合性能的研究已有报道。Blasius等将二苯并18-冠-6与甲醛或与苯酚及甲醛缩聚,得到冠醚高聚物可作为离子交换剂。
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| 收稿时间： | 1982-09-28 |
STUDIES ON THE SATURATED URUSHIOL CROWN ETHER |
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| Huang Zai-fu,Shu Jia-you,Yu Zong-yuan.STUDIES ON THE SATURATED URUSHIOL CROWN ETHER[J].Acta Polymerica Sinica,1984,0(3):220-222. |
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| Authors: | Huang Zai-fu Shu Jia-you Yu Zong-yuan |
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| Institution: | Department of Chemistry; Wuhan University |
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| Abstract: | Saturated urushiol, obtained from the Chinese Lacquer by direct catalytic hydrogenation, was condensed with polyethylene glycol dichloride or 1,2-di (polyethylene chloride) benzene to form the saturated urushiol crown ethers. Three new crosslinked polymeric saturated urushiol crown ethers were synthesized via reaction of these monomeric crown ethers with formaldehyde or formaldehyde and phenol in the presence of H2SO4 as a catalyst. The complex-ing capacity, catalytic acitivity and thermostabililty of these polymers have also been investi-gated. |
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