Non-steady-state living polymerization: a new route to control cationic ring-opening polymerization (CROP) of oxetane via an activation chain end (ACE) mechanism at ambient temperature |
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| Authors: | Bouchékif Hassen Philbin Marcia I Colclough Eamon Amass Allan J |
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| Institution: | School of Chemical Engineering & Applied Chemistry, Aston University, Birmingham B47ET, UK. hbouchekif@yahoo.fr |
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| Abstract: | Well-defined polyoxetane with low polydispersivity has been synthesized via a novel living polymerisation process using 3-phenoxypropyl 1,4-dioxanium hexafluoroantimonate (3-PPD) as a model of a living "monomeric polyoxetane" initiator, in 1,4-dioxane at 35 degrees C. |
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