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Unconventional domain band structure at the crack tip in ferroelectric ceramics
Authors:W Yang  H T Wang  F Fang  Y Q Cui
Abstract:Domain polarization switch near the tip of a crack or an electrode plays a critical role in the fracture or toughening of ferroelectric ceramics. The intensive electric field near a crack tip stimulates local domain switching. Experiment indicates that the domain band structure in front of an indentation crack under lateral electric loading is unconventional, attributed to the highly localizing crack tip electric field. The partially switched ferroelectric grain resembles a banded Eshelby inclusion embedded in a polycrystalline ferroelectric matrix. The domain wall energy for unconventional domain structures is estimated via arrays of misfit dislocations. Mesomechanics analysis quantifies the unconventional domain band structures. The predicted parameters include the volume fraction, the thickness, and the orientation of switched domain bands.
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