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Codoping Na+ to modulate the spectroscopy and photoluminescence properties of Yb3+ in CaF2 laser crystal
Authors:Su Liangbi  Xu Jun  Li Hongjun  Yang Weiqiao  Zhao Zhiwei  Si Jiliang  Dong Yongjun  Zhou Guoqing
Affiliation:Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Qinghe Road 390, Jiading, Shanghai 201800, China. su_lb@163.com
Abstract:Three kinds of Yb3+ - and Na+-codoped CaF2 laser crystal with different Na:Yb ratios of 0, 1.5, and 10 are grown by the temperature gradient technique. Room-temperature absorption, photoluminescence spectra, and fluorescence lifetimes belonging to the transitions between ground state 2F7/2 and excited state 2F5/2 of Yb3+ ions in the three crystals are measured to study the effect of Na+. Experimental results show that codoping Na+ ions in different Na:Yb ratios can modulate the spectroscopy and photoluminescence properties of Yb3+ ions in a CaF2 lattice in a large scope.
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