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Organometallic chemistry in the melt phase |
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| Authors: | Muhammad D Bala [Author Vitae] [Author Vitae] |
| Institution: | Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Johannesburg 2050, South Africa |
| Abstract: | In this review organometallic chemistry reactions in the melt phase are described. As will be indicated this is a viable approach to make new and known complexes. Examples from the literature highlighting procedures used to generate melts and results that have been obtained in this area of synthesis are described. Clearly there will be limitations to the use of the melt phase, and these limitations are also discussed. |
| Keywords: | diag Diagonal DGV differential thermogas volumetry DSC differential scanning calorimetry DTA differential thermal analysis DRIFTS diffuse reflectance infrared spectroscopy DTG differential TG EDXRD energy dispersive X-ray diffraction en ethylenediamine Fc ferrocene ferrocenyl IR Infra-red iPr iso-propyl lat Lateral L Donor ligand M transition metal Me methyl m p melting point NMR nuclear magnetic resonance phen phenanthroline Ph phenyl PR3 phosphine e g PPh3 P(OR)3 phosphite e g P(OiPr)3 PXRD powder- X-ray diffraction R organic group r t room temperature SCXRD Single crystal- X-ray diffraction STA simultaneous thermal analysis (DTA TG DTG) TGA thermogravimetric analysis tBu tert-butyl X halogen |
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