| 用非等温DSC估算3,4-双(4’-硝基呋咱-3’-基)-2-氧化呋咱(BNFOF)放热自催化分解反应的热爆炸临界温升速率和动力学参数 |
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| 引用本文： | 赵凤起,郭鹏江,胡荣祖,张海,XIA,夏志明,高红旭,陈沛,罗阳,张志忠,周彦水,赵宏安,高胜利,史启祯,路桂娥,江劲.用非等温DSC估算3,4-双(4’-硝基呋咱-3’-基)-2-氧化呋咱(BNFOF)放热自催化分解反应的热爆炸临界温升速率和动力学参数[J].中国化学,2006,24(5):631-636. |
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| 作者姓名： | 赵凤起 郭鹏江 胡荣祖 张海 XIA 夏志明 高红旭 陈沛 罗阳 张志忠 周彦水 赵宏安 高胜利 史启祯 路桂娥 江劲 |
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| 作者单位： | [1]Xi＇an Modern Chemistry Research Institute, Xi＇an, Shaanxi 710065, China [2]Shaanxi Key Laboratory of Physico-inorganic Chemistry and Department of Chemistry, Northwest University, Xi＇an, Shaanxi 710069, China [3]Department of Mathematics, Northwest University, Xi＇an, Shaanxi, 710069, China [4]Ordnance Engineering Institute, Shijiazhuang, Hebei 050000, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20573098）, the Science and Technology Foundataon of the National Defence Key Laboratory of Propellant and Explosive Combustion of China （No. 51455010）. |
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| 摘 要： | A method of estimating the kinetic parameters and the critical rate of temperature rise in the thermal explosion for the autocatalytic decomposition of 3,4-bis（4＇-nitrofurazan-3＇-yl）-2-oxofurazan （BNFOF） with non-isothermal differential scanning calorimetry （DSC） was presented. The rate equation for the decomposition of BNFOF was cstablished, and information was obtained on the rate of temperature increase in BNFOF when the empiric-order autocatalytic decomposition was converted into thermal explosion.
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| 关 键 词： | 动力学参数 3 4-二（4＇-硝基呋喃氨基）-2-氧呋喃 BNFOF 自催化分解 热爆炸 |
| 收稿时间： | 2005-06-01 |
| 修稿时间： | 2005-06-012005-12-16 |
Estimation of the Kinetic Parameters and the Critical Rate of Temperature Rise in the Thermal Explosion from the Exothermic Autocatalytic Decomposition of 3,4‐Bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) Using Non‐isothermal Differential Scanning Calorimetry |
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| ZHAO Feng-Qi, GUO Peng-Jiang,HU Rong-Zu, ZHANG HaiC, XIA Zhi-Ming, GAO Hong-Xua, CHEN Pei,LUO Yang, ZHANG Zhi-Zhong ,ZHOU Yan-Shui, ZHAO Hong-Anb, GAO Sheng-Lib, SHI Qi-Zhenb, LU Gui-Ed,JIANG Jin-Yong.Estimation of the Kinetic Parameters and the Critical Rate of Temperature Rise in the Thermal Explosion from the Exothermic Autocatalytic Decomposition of 3,4‐Bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) Using Non‐isothermal Differential Scanning Calorimetry[J].Chinese Journal of Chemistry,2006,24(5):631-636. |
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| Authors: | ZHAO Feng-Qi GUO Peng-Jiang HU Rong-Zu ZHANG HaiC XIA Zhi-Ming GAO Hong-Xua CHEN Pei LUO Yang ZHANG Zhi-Zhong ZHOU Yan-Shui ZHAO Hong-Anb GAO Sheng-Lib SHI Qi-Zhenb LU Gui-Ed JIANG Jin-Yong |
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| Abstract: | A method of estimating the kinetic parameters and the critical rate of temperature rise in the thermal explosion for the autocatalytic decomposition of 3,4‐bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) with non‐isothermal differential scanning calorimetry (DSC) was presented. The rate equation for the decomposition of BNFOF was established, and information was obtained on the rate of temperature increase in BNFOF when the empiric‐order autocatalytic decomposition was converted into thermal explosion. |
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| Keywords: | 3 4‐bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) autocatalytic decomposition kinetic parameter critical rate of temperature rise thermal explosion non‐isothermal DSC |
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