Halogen-induced selectivity in heterogeneous epoxidation is an electronic effect--fluorine,chlorine, bromine and iodine in the Ag-catalysed selective oxidation of ethene |
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| Authors: | Lambert Richard M Cropley Rachael L Husain Alifiya Tikhov Mintcho S |
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| Affiliation: | Department of Chemistry, University of Cambridge, Lensfield Rd, Cambridge, UK CB2 1EW. RML1@cam.ac.uk |
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| Abstract: | Selectivity promotion in the Ag-catalysed heterogeneous epoxidation of ethene correlates with halogen electron affinity showing that it is an electronic phenomenon rather than a steric or geometrical effect. |
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