Towards "designer" surfaces: functionalisation of self-assembled monolayer (SAM) on colloidal gold by alkene metathesis |
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Authors: | Samanta Debasis Faure Nicolas Rondelez Francis Sarkar Amitabha |
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Affiliation: | Division of Organic Chemistry (Synthesis), National Chemical Laboratory, Pune-411 008, India. |
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Abstract: | A variety of groups like a Fischer carbene complex, an N-hydroxysuccinimide or a ferrocene derivative have been grafted by ruthenium-catalyzed cross-metathesis reaction with terminal alkene groups on monolayer-protected gold clusters as a mild and convenient strategy to anchor functional molecules. |
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