Reductive cleavage of the C-O bond of acetals and orthoesters: reduction by silane in the presence of a Rh-PPh3 complex |
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| Authors: | Ohta Tetsuo Michibata Tsugumi Yamada Kazuyuki Omori Ryohei Furukawa Isao |
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| Institution: | Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0394, Japan. tota@mail.doshisha.ac.jp |
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| Abstract: | Reductions of acetals to ethers and of orthoester to acetal by hydrosilane using rhodium catalyst are described. |
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