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Sensitised near-infrared emission from lanthanides using a covalently-attached Pt(II) fragment as an antenna group
Authors:Shavaleev Nail M  Moorcraft Lucy P  Pope Simon J A  Bell Zöe R  Faulkner Stephen  Ward Michael D
Institution:School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS.
Abstract:In a series of heterodinuclear complexes in which a Pt(PPh3)2(catecholate) chromophore is covalently linked to a lanthanide tris(diketonate) unit, sensitised near-IR emission from Yb(III), Nd(III) and Er(III) occurs on excitation of the Pt(II) chromophore at 520 nm.
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