Abstract: | We report electron and Na+ ion emission from single-crystal sodium nitrate (~10 eV band gap) upon exposure to IR (1064 nm, 1.16 eV) laser radiation. The fluence dependence of both the ion and the electron yield is highly nonlinear, and the kinetic energies of the emitted ions can reach values up to 5 eV. The fluence dependence and the ion energy distributions can be understood by a previously presented model involving multiple photon charge transfer plus electrostatic ejection of adions siting atop electron traps. Further evidence for the role of defects in the observed ion emission are provided by two-beam experiments; one beam (UV laser) is used to generate defects and the second beam (IR laser) is used to photodesorb the ions. Such experiments demonstrate that exposure of the sodium nitrate surfaces to UV laser radiation significantly increases the ion emission due to IR laser radiation. |