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(R)-4-Menthenone in the synthesis of optically pure sex pheromone of the peach leafminer moth (Lyonetia clerkella)
Authors:Kharisov  R Ya  Latypova  E R  Talipov  R F  Muslukhov  R R  Ishmuratov  G Yu  Tolstikov  G A
Institution:(1) Institute of Organic Chemistry of the Ufa Scientific Center of the Russian Academy of Sciences, 71, prosp. Oktyabrya, 450054 Ufa, Russian Federation;(2) Bashkir State University, 32, ul. Frunze, 450074 Ufa, Russian Federation
Abstract:The synthesis of (14S)-methyloctadec-1-ene, sex pheromone of the peach leafminer moth (Lyonetia clerkella), is described to demonstrate a new potential of the synthetic use of (R)-4-menthenone.
Keywords:(–  )-menthol  (R)-4-menthenone  (5R  1RS)-1-ethyl-2-isopropyl-5-methylcyclohex-2-enol  (S)-3-ethyl-2-isopropyl-5-methylcyclohex-2-enone  methyl (3S)-methyl-5-oxoheptanoate  (14S)-methyloctadec-1-ene  ozonolysis  CrVI oxidation  insect pheromones
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