An optical spectroscopic study of borate glasses containing uranium ions |
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Authors: | E. Culea I. Milea Maria Rusu Monica Culea |
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Affiliation: | (1) Technical University of Cluj-Napoca, str. C. Daicoviciu nr. 15, 3400 Cluj-Napoca, Romania;(2) Faculty of Chemistry, Babes-Bolyai University of Cluj-Napoca, str. Arany J, nr 10, 3400 Cluj-Napoca, Romania;(3) Institute of Isotopic and Molecular Technology, str. Donath nr. 105, 3400 Cluj-Napoca, Romania |
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Abstract: | An optical spectroscopic investigation has been performed on some borate glasses containing 1mol% UF4, UO2 and UO3. The optical data confirm the presence of uranium ions in valence stages of +6, +5 and +4. The influence of the composition of the glass matrix and of the -irradiation on the redox equilibrium of uranium ions was discussed. |
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