| 对甲苯磺酰谷氨酸桥联的一维双链锰配合物的合成、表征与晶体结构 |
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| 引用本文： | 陈满生,梁福沛,胡瑞祥,马运声,宋丽华.对甲苯磺酰谷氨酸桥联的一维双链锰配合物的合成、表征与晶体结构[J].无机化学学报,2005,21(5):689-692. |
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| 作者姓名： | 陈满生 梁福沛 胡瑞祥 马运声 宋丽华 |
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| 作者单位： | 1. 广西师范大学化学化工学院,桂林,541004;衡阳师范学院化学与材料科学系,衡阳,421008
2. 广西师范大学化学化工学院,桂林,541004 |
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| 基金项目： | 广西自然科学基金资助项目(No.0229004)。 |
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| 摘 要： | A one-dimensional double-chain coordination polymer Mn(phen)(tsgluo)] was synthesized in a mixed solution and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic system with space group P212121. The crystal data are: a=0.530 78(17) nm, b=1.723 9(5) nm, c=2.456 9(8) nm, Z=4, μ=0.729 mm-1, Dc=1.579 g·cm-3, V=2.248 1(12) nm3, R1=0.033 1, ωR2=0.078 9. In the title complex, each Mn(Ⅱ) ion presents a octahedral geometry with the coordination of two nitrogen atoms from 1,10-phenanthroline and four oxygen atoms from three different tsgluo2- ligands. The γ-carboxyl coordinates to Mn(Ⅱ) in the mode of bidentate chelate, while the α-carboxyl coordinates in a bidentate bridging mode. CCDC: 253910.
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| 关 键 词： | 对甲苯磺酰谷氨酸 锰配合物 晶体结构 |
| 文章编号： | 1001-4861(2005)05-0689-04 |
| 收稿时间： | 7/5/2004 12:00:00 AM |
| 修稿时间： | 2004年7月5日 |
Synthesis, Characterization and Crystal Structure of a 1D Double-chain Manganese Complex Bridged by N-p-tolysulfonyl-L-glutamic Acid |
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| CHEN Man-Sheng,LIANG Fu-Pei,HU Rui-Xiang,MA Yun-Sheng and SONG Li-Hua.Synthesis, Characterization and Crystal Structure of a 1D Double-chain Manganese Complex Bridged by N-p-tolysulfonyl-L-glutamic Acid[J].Chinese Journal of Inorganic Chemistry,2005,21(5):689-692. |
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| Authors: | CHEN Man-Sheng LIANG Fu-Pei HU Rui-Xiang MA Yun-Sheng and SONG Li-Hua |
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| Institution: | College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004;Department of Chemistry and Material Science, Hengyang Normal College, Hengyang 421008,College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004,College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004,College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004 and College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004 |
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| Abstract: | |
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| Keywords: | N-p-tolysulfonyl-L-glutamic acid manganese complex crystal structure |
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