Anionization of volatile molecules on the surface of electrolytic solutions exposed to high electric fields |
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| Authors: | K H Ott F W Rllgen P Dhling J J Zwinselman R H Fokkens N M M Nibbering |
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| Institution: | K. H. Ott,F. W. Röllgen,P. Dähling,J. J. Zwinselman,R. H. Fokkens,N. M. M. Nibbering |
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| Abstract: | The anionization of molecules supplied from the gas phase onto a negatively charged Cl]? or NO3]? ion donating surface has been investigated. The charged surface was prepared by exposing an aqueous solution of LiCl (or LiNO3) and polyethylene oxide to a high external field as is done in negative ion field desorption mass spectrometry. The ionization of some monosaccharides and adenosine by Cl]? and NO3]? attachment and of some acids by proton abstraction is reported. |
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