Massenspektrometrische Messung der Stabilität der gasförmigen Komplexe MAl2Cl8 (M  Be,Fe, Zn,Cd, Pt) Der Zusammenhang der Stabilität der Gaskomplexe MAl2Cl8 mit den Koordinationszahlen im festen Dichlorid

Mass Spectrometric Measurements of the Stability of the Gaseous Complexes MAl₂Cl₈ (M ? Be, Fe, Zn, Cd, Pt). Connection between the Stability of the Complexes MAl₂Cl₈ and the Coordination of M and Cl in the Solid Dichloride The equilibria MCl_2,s + Al₂Cl_6,g ? MAl₂Cl_8,g mit (M ? Fe, Zn, Cd, Pt) have been measured by mass spectrometry (effusion from double cells). The corresponding equilibrium with BeCl₂ has been calculated from older measurements. All the ΔH° and ΔS° data of this type of reaction have been collected from the literature. A clear connection exists between the thermodynamic data and the coordination of M and Cl in the solid dichlorides.