Bildung siliciumorganischer Verbindungen. 87. Das 2,8,9-Trioxa-1,3,5,7-tetrasilaadamantan |
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Authors: | G. Fritz K. Gompper |
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Abstract: | Formation of Organosilicon Compounds. 87. 2,8,9-Trioxa-1,3,5,7-Tetrasilaadamantane Hydrolysis of cis-cis-1,3,5-tribromo-1,3,5-tri-t-butyl-1,3,5-trisilacyclohexane yields the trisilanole 2 (mp. 205°C) which forms the tetrasilaadamantane 3 with SiCl4/et2NH. Hydrolysis of 3 yields 4 (Formulae see “Inhaltsübersicht”). |
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