Gleichgewichtsmessungen mit den Systemen PdX2,f + Al2X6,g = PdAl2X8,g (X = Cl,Br, I) |
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Authors: | Heinz-Bernhard Merker Harald Schfer |
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Institution: | Heinz-Bernhard Merker,Harald Schäfer |
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Abstract: | Equilibrium Measurements with the Systems PdX2.f + Al2X6.g = PdAl2X8.g; (X = Cl, Br, I) The equilibria mentioned on the title have been measured by a simple flow method. In contrast with the data measured with X = Cl or Br, for X = I only less accurate, informing values could be obtained. Even so differences in the stability of chloride and bromide complexes on one hand and iodide complexes on the other hand can be traced back on differences in the structures of the solid dihalides. |
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