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Carbon-13 NMR spectra of some epoxides derived from dicyclopentadiene
Authors:Yasuhiro Matoba  Takashi Kagayama  Yasutaka Ishii  Masaya Ogawa
Abstract:The 13C NMR spectra of a series of epoxides derived from endo- and exo-dicyclopentadiene and their partially hydrogenated compounds were determined to examine the substituent effects arising from the introduction of the oxirane ring in comparison with those found in other ring systems. The 13C signals of some epoxides were assigned by using lanthanide shift reagents. Characteristic substituent effects exerted by an oxirane ring were demonstrated. Marked steric γ-effects of ?8—13 ppm were observed at the bridge carbon signal in the bicyclo2.2.1]heptane skeleton. Differences were found in the substituent effects between endo- and exo-dicyclopentadiene epoxides, and have been discussed in relation to the molecular geometry.
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