Tetrameric Cubic Structures of Two Solvated Lithium Enolates |
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| Authors: | Ren Amstutz,W. Bernd Schweizer,Dieter Seebach,Jack D. Dunitz |
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| Affiliation: | René Amstutz,W. Bernd Schweizer,Dieter Seebach,Jack D. Dunitz |
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| Abstract: | The structures of the crystalline lithium enolates derived from 3, 3-dimethyl-2-butanone and from cyclopentanone have been determined by X-ray analysis. Both structures are tetrameric aggregates based on a Li4O4-cube, each Li+-ion being additionally bonded to the O-atom of a tetrahydrofuran solvent molecule. |
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