A new dual-type DMA for measuring nanoparticles emitted from combustion engines

A new dual-type differential mobility analyzer (dual-type DMA) was developed in order to detect transient number concentrations of airborne nanoparticles with diameters centralized at around 10 nm (for nuclei mode particles) and 100 nm (for accumulation mode particles) in automobile exhaust gas. The apparatus divides the gas sample into two parts, and each part is sent through one of two coaxially nested sections for analysis. For the scanning mode measurement, the nanoparticles are charged by ²⁴¹Am and their size distributions are determined by varying the applied voltage over 2 min. The transient mode measurement, on the other hand, fixes the voltages for the two sections at peaks near 10 and 100 nm in order to monitor the transient behavior of the exhaust nanoparticles. The measurement principles and design of the dual-type DMA are detailed and the results for time response experiments are presented using model nanoparticles charged by a corona charger. The transient concentrations of the nuclei mode and the accumulation mode particles from a diesel engine were shown to be detected by this method, when ²⁴¹Am was used for charging the particles.