Total synthesis of (+)-cyanthiwigin U |
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| Authors: | Pfeiffer Matthew W B Phillips Andrew J |
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| Institution: | Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, USA. |
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| Abstract: | A concise total synthesis of the tricyclic terpene cyanthiwigin U has been accomplished in 12 steps and 17% overall yield. The key step of the synthesis is a two-directional tandem metathesis reaction that forms the cycloheptae]indene core from a readily available bicyclo2.2.2]octene. |
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