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Structural and optical properties of thin films of Cu(In,Ga)Se2 semiconductor compounds
Authors:A. V. Mudryi   V. F. Gremenok   A. V. Karotki   V. B. Zalesski   M. V. Yakushev   F. Luckert  R. Martin
Affiliation:1.Scientific and Applied Materials Research Center,National Academy of Sciences of Belarus,Minsk,Belarus;2.B. I. Stepanov Institute of Physics,National Academy of Sciences of Belarus,Minsk,Belarus;3.Strathclyde University,Glasgow,UK
Abstract:The chemical composition of Cu(In,Ga)Se2 (CIGS) semiconductor compounds is analyzed by local x-ray spectral microanalysis and scanning Auger electron spectroscopy. X-ray diffraction analysis reveals a difference in the predominant orientation of CIGS films depending on the technological conditions under which they are grown. The chemical composition is found to have a strong effect on the shift in the self-absorption edge of CIGS compounds. It is shown that a change in the relative proportion of Ga and In in CIGS semiconducting compounds leads to a change in the band gap Eg for this material in the 1.05–1.72 eV spectral range at 4.2 K.
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