|
|||||
|
|
| The structure and magnetic properties of μ_3-oxotriiron(Ⅲ) complex [Fe_3O(OBz)_6(CH_3OH)_3](NO_3)(CH_3OH)_2 | |
| 作者姓名： | FU De-Gang WANG Guo-Xiong TANG Wen-XiaState Key Laboratory of Coordination Chemistry Nanjing University Nanjing Jiangsu 210008 ChinaYU Kai-BeiAnalysis center Chengdu Branch of Chinese Academy of Science Chengdu 610015 China |
| 作者单位： | FU，De-Gang WANG，Guo-Xiong TANG，Wen-XiaState Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210008，ChinaYU，Kai-BeiAnalysis center，Chengdu Branch of Chinese Academy of Science，Chengdu 610015，China |
| 摘 要： | A new μ3-O triiron(Ⅲ) complex [Fe_3O(OBz)_6(CH_3OH)_3](NO_3)(CH_3OH)_2 (HOBZ = benzoic acid) has been synthesized, its structure has been determined and variable temperature magnetic susceptility has also been measured. In the molecule, three iron atoms formed an equilateral triangle with u_3-O in center. The fitting to the magnetic susceptibility showed that an intramolecular antiferromagnetic exchange interaction occurred between iron atoms with J=-25.51 cm~(-1), and a weaker intermolecular antiferromagnetic exchange interaction occurred with zJ' = -2.30cm~(-1). |
| 本文献已被 CNKI 等数据库收录！ | |