Transformations of 2-(2-thiocyanatoalkoxy)-1,3,2-dioxaphospholanes |
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Authors: | O N Nuretdinova L B Troitskaya |
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Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR |
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Abstract: | In contrast to the case of 2-(2-haloalkoxy)-1,3,2-dioxaphospholanes, the coordination of the phosphorus atom in analogous esters with an SCN group is altered under mild conditions involving the sulfur atom with formation of spirophosphoranes with a 1,3,2-oxathiaphospholane fragment.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 950–951, April, 1991. |
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