Depletion potentials between colloids and patterned surfaces |
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Authors: | Pawe? Bryk Stefan Soko?owski |
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Affiliation: | Department for the Modeling of Physico-Chemical Processes, Maria Curie-Sk?odowska University, 20-031 Lublin, Poland |
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Abstract: | Effective interactions between the hard-sphere colloids and the patterned substrates created by depositing one or more hemispheres on the structureless walls are studied. The deposition of only one hemispherical cap gives rise to a new global minimum of the depletion potential but the difference from the planar hard wall case is moderate. On the other hand, when the hemispherical caps form a periodic array, multiple overlaps of the excluded volumes lead to formation of deep global minimum of the depletion potential. In some cases this minimum is deeper than −10kBT and this is more than triple of the potential minimum for the structureless wall. We conclude that templated surfaces affect depletion potentials significantly. This effect will have a major impact even when the residual attractive/repulsive interactions are present. |
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Keywords: | 82.70.Dd 61.20.Gy |
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