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Effect of thermal annealing on microstructural properties of Ti/Ge2Sb2Te5/Ti thin films deposited on SiO2/Si substrates by a sputtering method
Authors:SY Kim  IS Chung  JY Lee
Institution:a Department of Materials Science & Metallurgy, Kyungpook National University, Daegu 702-701, Republic of Korea
b Department of Materials Science & Engineering, KAIST, Daejeon 305-701, Republic of Korea
c Advanced Semiconductor Research Center, Division of Electrical and Computer Engineering, Hanyang University, Seoul 133-791, Republic of Korea
Abstract:Ti/Ge2Sb2Te5/Ti thin films deposited by a sputtering method on SiO2/Si substrates were annealed at 400 °C in N2 atmosphere and characterized by using transmission electron microscopy (TEM) and Auger electron spectroscopy (AES) in order to investigate the inter-diffusion of the Ti/Ge2Sb2Te5/Ti system due to annealing. The TEM and AES results showed that the interface between the Ti and the Ge2Sb2Te5 layers was unstable and Ti atoms were incorporated into the Ge2Sb2Te5 thin film upon annealing. The Te and Sb atoms of the Ge2Sb2Te5 layer diffused into the Ti layer. The intermixing layers between the Ge2Sb2Te5 layer and two Ti layers were formed. These results indicate that the microstructural properties of the Ti/Ge2Sb2Te5/Ti systems can be degraded by the postgrowth thermal annealing.
Keywords:68  37  Lp  68  55  Jk  61  50  Ks
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