Synthesis and transformations of 1,3,5-triazabicyclo[3.1.0]hexanes期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Synthesis and transformations of 1,3,5-triazabicyclo[3.1.0]hexanes

Authors:	N. N. Makhova A. N. Mikhailyuk A. E. Bova T. V. Chabina L. I. Khmel'nitskii

Affiliation:	(1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation

Abstract:	The conditions for the condensation of 1,2-nonsubstituted diaziridines with CH₂O and NH₃ (or AlkNH₂) to the corresponding 1,3,5-triazabicyclo[3.1.0]hexanes have been found and 3-phenylsulfonyl, 3-trimethylsilyl, 3-nitroso, and 3-nitro derivatives of the latter have been obtained.For the previous communication, see Ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2091–2095, December, 1993.

Keywords:	diaziridines, condensation 1,3,5-triazabicyclo[3.1.0]hexanes, /content/x76ktr11u4635628/xxlarge945.gif" alt=" agr" align=" BASELINE" BORDER=" 0" >-aminomethylation, nitrosation, denitrosation, silylation, nitration
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