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阴极催化剂对微生物燃料电池性能的影响
引用本文:阴极催化剂对微生物燃料电池性能的影响. 阴极催化剂对微生物燃料电池性能的影响[J]. 燃料化学学报, 2017, 45(10): 1275-1280
作者姓名:阴极催化剂对微生物燃料电池性能的影响
作者单位:State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing 400044, China
基金项目:重庆市基础与前沿研究计划重点项目(CSTC,2013jjB20001;CSTC,2015jcyjBX0015)资助
摘    要:以不同载量的MnO_2/rGO和Pt/C修饰阴极电极构建了生物阴极型双室微生物燃料电池(MFC),考察了不同阴极催化剂修饰MFC对其产电性能以及老龄垃圾渗滤液主要污染物去除效果的影响。结果表明,以MnO_2/rGO修饰MFC阴极电极材料,能显著提高MFC产电性能及对老龄垃圾渗滤液中污染物去除效果;输出电压为372 mV,功率密度为194 mW/m~3(是未经催化剂修饰MFC的两倍),内阻为264Ω,化学需氧量(COD)和氨氮(NH_3-N)去除率分别为58.68%和76.64%。当MnO_2/rGO载量为.0 mg/cm~2时,MFC性能与负载Pt/C的MFC性能接近,但构建成本却明显降低。

关 键 词:微生物燃料电池  阴极催化剂  老龄垃圾渗滤液  产电特征  废水处理  
收稿时间:2017-03-21

Effects of cathode catalyst modification on the performance of microbial fuel cells
XIE Miao,XU Long-jun,HU Jin-feng,XU Yan-zhao. Effects of cathode catalyst modification on the performance of microbial fuel cells[J]. Journal of Fuel Chemistry and Technology, 2017, 45(10): 1275-1280
Authors:XIE Miao  XU Long-jun  HU Jin-feng  XU Yan-zhao
Abstract:Bio-cathode microbial fuel cells (MFCs) were modified with MnO2/rGO and Pt/C; the effects of cathode catalyst modification on the performance of microbial fuel cells in electricity production and aged landfill leachate treatment were investigated. The results show that the MFC modified with MnO2/rGO can significantly enhance the electricity production and the removal of contaminants. The MFC modified with 1.0 mg/cm2 MnO2/rGO exhibits a harvest voltage of 372 mV, power density of 194 mW/m3, chemical oxygen demand removal rate of 58.68%, and ammonia removal rate of 76.64%; such a performance is similar to that modified with Pt/C, but the cost is greatly reduced.
Keywords:microbial fuel cell  catalyst modified cathode  aging landfill leachate  electricity production  wastewater treatment  
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