Metathesis of allylsilanes with aromatic substituents |
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| Authors: | V M Vdovin N V Ushakov E B Portnykh E Sh Finkel'shtein N P Abashkina |
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| Institution: | (1) A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The feasibility was demonstrated for the efficient metathesis of phecyltolyl- and benzylallylsilanes on an alumorhenium catalyst promoted by tetrabutyltin. The metathesis of aryldimethylallylsilanes or aralkyldimethylallylsilanes is a preparative method for the synthesis of 1,4-bis(aryldimethylsilyl)-2-butenes or 1,4-bis(aralkyldimethylsilyl)-2-butenes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2121–2123, September, 1984. |
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